Trim any excess fat and pat the chops dry with a paper towel to ensure a good sear. Season generously with salt, pepper, and smoked paprika on both sides. Heat olive oil over medium-high heat in a cast iron skillet until shimmering. Place pork chops in the pan without overcrowding. Sear for 3-4 minutes on each side, until a golden crust forms. Reduce heat to medium and add butter to the pan. Stir in minced garlic and baste the chops with the melted butter for 1-2 minutes. Use a meat thermometer to ensure the internal temperature reaches 145°F. Remove the chops from the pan and let them rest for 5 minutes before serving.